...$ k_{298}$4.1
Units for first order reactions are s$ ^{-1}$, for the second-order gas reactions are molecules$ ^{-1}$ cm$ ^3$ s$ ^{-1}$, for the third-order gas reactions molecules$ ^{-2}$ cm$ ^6$ s$ ^{-1}$, and for the second-order aqueous reactions are M$ ^{-1}$ s$ ^{-1}$. Units for solubility constants are M atm$ ^{-1}$, and units for dissociation constants are M. Reaction rates are of the form $ k = k_{298} \hbox{exp}[-{E \over R} ({1 \over T} - {1 \over 298})]$ unless otherwise noted.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
... &Reference4.2
NASA97, Demore et al. [49]; Y90, Yin et al. [195,194]; HC85, Hoffmann and Calvert [72]; LK86, Lind and Kok [112]; NBS65, National Bureau of Standards [131]; and M82, Maahs [117].
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
... MSA4.3
Here $ k = {{Te^{-234/T} + 8.46\times10^{-10}
e^{7230/T} + 2.68\times10^{-10}e^{7810/T}} \over {1.04\times10^{11}T +
88.1e^{7460/T} }}$.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
... 4.4
Here $ k = {{k_{298}\hbox{exp}[-{E \over R}
({1 \over T} - {1 \over 298})] [H^+]} \over {1 + 13[H^+]}}$.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
... time.6.1
Mid-month concentrations are input and then interpolated to daily values. The input data are constructed to correctly recover the observed monthly means value using the method of Taylor et al. [170]
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.